9.8.3. Appendix 9.3: Thermodynamics and Kinetics Parameters of Fuel Clad Chemical Interaction Model

Lanthanide Migration

The solubility limit of lanthanides in metallic fuel is assumed to be zero [9‑4]. The lanthanide diffusion coefficient is given in Eq. (9.8-4), where \(S_{Dla}\) is the user defined sensitivity coefficient, SCDLA. Below 800 K, the temperature is set to 800 K in order to account for the irradiation-induced diffusivity. Ref. [9‑5] is used to assess the solubility limit of lanthanides. Thermodynamic and kinetics parameters related the lanthanide diffusion and precipitation model are given in Table 9.8.5. Note that solubility limit of D9 cladding is reduced significantly compared to the HT9 cladding in order to account for excessive clad wastage behavior observed in experiments. Diffusion constant and diffusion activation energy is used as fitting factors.

(9.8-3)\[\begin{split} D_{la} = \begin{cases} S_{Dla} D_0 exp\left( - \frac{Q_0}{RT} \right) & T \ge 750 \text{ K} \\ S_{Dla} D_0 exp\left( - \frac{Q_0}{750R} \right) & T \leq 750 \text{ K} \\ \end{cases}\end{split}\]
Table 9.8.5 Diffusion coefficient, heat of transport, and Lanthanide yield for Lanthanide migration

\(D_{0}\) (m \(^2\)/s)

10000.0

\(Q_{0}\) (kJ/mol)

300.0

\(Y_{la}\) (#/J)

\(15.29E+09\)

Solubility in HT9 (atom/ \(m^{3}\))

\(6.4E+27\)

Solubility in D9 (atom/ \(m^{3}\))

\(0.5E+27\)

Solubility in SS316 (atom/ \(m^{3}\))

\(0.5E+27\)

Solubility in 15-15Ti (atom/ \(m^{3}\))

\(0.5E+27\)

Iron and Actinide Migration

The iron and actinide diffusion coefficients are calculated using the relationships given in Eq. (9.8-4) and Eq. (9.8-5), respectively, where \(S_{Dac}\) is the user defined sensitivity coefficient, SCDAC. Table 9.8.6 and Table 9.8.8 gives the diffusion constant and activation energy values. Table 9.8.9 and Table 9.8.10 gives the thermodynamics and kinetics parameters used in iron and actinide diffusion and eutectic formation. The experimental observartions in Ref. [9‑6] is used to extract thermodynamics and kinetics parameters.

(9.8-4)\[D_{Fe} = D_{0Fe} exp \left( - \frac{Q_{0Fe}}{RT} \right)\]
(9.8-5)\[ D_{Ac} = S_{Dac} D_{0Ac} exp \left( - \frac{Q_{0Ac}}{RT} \right)\]
Table 9.8.6 Diffusion constant and activation energy for iron diffusion in metal fuel

Parameter

T < \(T_{\beta + \gamma }\)

T \(\geq T_{\beta + \gamma }\)

\(D_{0Fe}\) (m \(^2\)/s)

0.225E-04

1.0E-04

\(Q_{0Fe}\) (kJ/mol)

220

220
Table 9.8.7 Diffusion constant and activation energy for iron diffusion in cladding

\(D_{0Fe}\) (m \(^2\)/s)

8.5E-04

\(Q_{0Fe}\) (kJ/mol)

251
Table 9.8.8 Diffusion constant and activation energy for Actinides and eutectic

Parameter

T < 1074.15 K

1074.15 K \(\leq\) T \(\leq\) 1094.15 K

T \(\geq\) 1094.15 K

\(D_{0Ac}\) (m \(^2\)/s)

2.2E-08

\(2.2E-08 + 3.3E-08 \frac{T-1075.15}{20}\)

5.5E-08

\(Q_{0Ac}\) (kJ/mol)

120

120

120
Table 9.8.9 Thermodynamics and kinetics parameters for iron, actinide diffusion, and eutectic formation

Phase Structure

Interaction Parameter

(J/mol)

Iron Solubility

Limit (%)

Phase growth activation

energy (kJ/mol)

(U,Pu)Fe2

-3000

66.7

220

Fe2Zr + (U,Pu)6Fe

-1200

40.5

220

(U,Pu)6Fe + U-32Zr-50Fe

-750

28.6

220

(U,Pu)6Fe + U-42Zr-33Fe

-650

21.8

220

U-Zr matrix + U-42Zr-33Fe

-500

13.2

220

U-Zr matrix + U-23Zr-6Fe

-800

2.5

220

(U,Pu)Zr

-800

0.0

220

Clad

-600

0.05

220

Eutectic

-1600

0.5

220
Table 9.8.10 Phase growth constansts (1/s) for iron, actinide diffusion, and eutectic formation

Phase Structure

T \(\le T_{\beta + \gamma}\)

T \(\geq T_{\beta + \gamma}\)

(U,Pu)Fe2

1.69E+05

7.5E+05

Fe2Zr + (U,Pu)6Fe

3.38E+05

1.5E+56

(U,Pu)6Fe + U-32Zr-50Fe

1.7E+06

7.5E+06

(U,Pu)6Fe + U-42Zr-33Fe

2.81E+06

1.25E+07

U-Zr matrix + U-42Zr-33Fe

3.94E+06

1.75E+07

U-Zr matrix + U-23Zr-6Fe

5.63E+07

1.5E+08

(U,Pu)Zr

0.0

0.0

Clad

0.0

0.0

Eutectic

2.81E+09

1.25E+10